| Final | | time | | L | | 1. Ewa Swoboda |  Poland | 7.09s | | 6 | | 2. Dafne Schippers |  Netherlands | 7.14s | SB | 5 | | 3. Asha Philip |  Great Britain | 7.15s | | 4 | | 4. Kristal Awuah | Great Britain | 7.15s | PB | 2 | | 5. Mujinga Kambundji |  Switzerland | 7.16s | | 3 | | 6. Maja Mihalinec |  Slovenia | 7.21s | PB | 8 | | 7. Krystsina Tsimanouskaya |  Belarus | 7.26s | | 1 | | 8. Ajla Del Ponte | Switzerland | 7.30s | | 7 |
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| World and European Record: Irina Privalova, Russia 6.92s Madrid, Spain 11 February 1993 | | World and European Record: Irina Privalova, Russia 6.92s Madrid, Spain 9 February 1995 | | Championship Record: Nelli Cooman, Netherlands 7.00s Madrid, Spain | 23 February 1986 | | World Leading: Marie-Josée Ta Lou, Ivory Coast 7.02s Düsseldorf, Germany 20 February 2019 | | European Leading: Ewa Swoboda, Poland 7.08s Karlsruhe, Germany 2 February 2019 | | Mujinga Kambundji, Switzerland 7.08s St. Gallen, Switzerlands 16 February 2019 |
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| | First 2 from each Semi and next Best 2 advanced to Final. |
| Semi 1 | | time | | | 1. Ewa Swoboda | Poland | 7.11s | Q | | 4. Mujinga Kambundji | Switzerland | 7.22s | Q | | 5. Kristal Awuah | Great Britain | 7.22s | q | | 10.Jamile Samuel | Netherlands | 7.31s | | | 11.Diana Vaisman |  Israel | 7.32s | NR | | 13.Carolle Zahi |  France | 7.35s | | | 14.Alexandra Toth |  Austria | 7.36s | | | 24.Estela García |  Spain | 7.46s | |
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| Semi 2 | | time | | | 3. Dafne Schippers | Netherlands | 7.19s | Q | | 9. Maja Mihalinic | Slovenia | 7.30s | Q | | 12.Ezinne Okparaebo |  Norway | 7.32s | | | 16.Rachel Miller | Great Britain | 7.37s | | | 17.Rebekka Haase |  Germany | 7.37s | | | 17.Klaudia Sorok |  Hungary | 7.39s | | | 19.Sarah Atcho | Switzerland | 7.41s | | | 21.Klára Seidlová |  Czechia | 7.41s | |
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| Semi 3 | | time | | | 2. Asha Philip | Great Britain | 7.19s | Q | | 6. Ajla Del Ponte | Switzerland | 7.25s | Q | | 7. Krystsina Tsimanouskaya | Belarus | 7.26s | q | | 8. Lisa Marie Kwayie | Germany | 7.29s | | | 14.Lorene Dorcas Bazolo |  Portugal | 7.35s | | | 19.Irene Ekelund |  Sweden | 7.41s | | | 22.Sindija Bukša |  Latvia | 7.42s | | | 23.Mathilde Kramer |  Denmark | 7.44s | |
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| | | First 3 from each Heat and next Best 6 advanced to Semi-Finals. |
| Heat 1 | | time | | | 2. Asha Philip | Great Britain | 7.23s | Q | | 9. Maja Mihalinec | Slovenia | 7.28s | Q, SB | | 18.Rebekka Haase | Germany | 7.36s | Q | | 23.Sindija Bukša | Latvia | 7.39s | q | | 26.Jaël Bestué | Spain | 7.41s | | | 34.Nasrana Bacar | France | 7.46s | |
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| Heat 2 | | time | | | 1. Ewa Swoboda | Poland | 7.14s | Q | | 8. Ezinne Okparaebo | Norway | 7.27s | Q, =SB | | 15.Alexandra Toth | Austria | 7.33s | Q | | 16.Jamile Samuel | Netherlands | 7.34s | q | | 32.Paula Sevilla | Spain | 7.44s | | | 36.Paraskevi Andreou |  Cyprus | 7.48s | | | -. Rafailía Spanoudáki-Hatziríga |  Greece | 162.7s | DQ |
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| Heat 3 | | time | | | 3. Rachel Miller | Great Britain | 7.24s | Q | | 11.Lisa Marie Kwayie | Germany | 7.30s | Q | | 21.Sarah Atcho | Switzerland | 7.38s | Q | | 24.Estela García | Spain | 7.40s | q | | 28.Mizgin Ay |  Turkey | 7.42s | | | 33.Zakiyya Hasanova |  Azerbaijan | 7.45s | | | 39.Monika Weigertová |  Slovakia | 7.54s | | | 41.Charlotte Wingfield |  Malta | 7.67s | |
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| Heat 4 | | time | | | 6. Krystsina Tsimanouskaya | Belarus | 7.27s | Q | | 7. Ajla Del Ponte | Switzerland | 7.27s | Q | | 20.Irene Ekelund | Sweden | 7.38s | Q | | 30.Marina Andreea Baboi |  Romania | 7.44s | | | 35.Milana Tirnanić |  Serbia | 7.47s | | | 37.Yana Kachur |  Ukraine | 7.52s | | | 38.Akvile Andriukaityte |  Lithuania | 7.54s | |
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| Heat 5 | | time | | | 10.Carolle Zahi | France | 7.29s | Q | | 12.Mujinga Kambundji | Switzerland | 7.31s | Q | | 13.Diana Vaisman | Israel | 7.33s | Q, NR | | 17.Mathilde Kramer | Denmark | 7.34s | q =NR | | 22.Klára Seidlová | Czechia | 7.39s | q | | 27.Patricia van der Weken |  Luxembourg | 7.41s | | | 40.Lauren Roy |  Ireland | 7.62s | |
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| Heat 6 | | time | | | 4. Dafne Schippers | Netherlands | 7.24s | Q | | 5. Kristal Awuah | Great Britain | 7.26s | Q | | 14.Lorène Dorcas Bazolo | Portugal | 7.33s | Q | | 19.Klaudia Sorok | Hungary | 7.37s | q, =PB | | 25.Helene Rønningen | Norway | 7.41s | =SB | | 29.Molly Scott | Ireland | 7.43s | | | 31.Elin Ŷ"stlund | Sweden | 7.44s | | | 42.Zyanne Hook |  Gibraltar | 8.49s | |
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